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Application of functional fillers in composites: Effects of fillers content on the mechanical properties
Krhut, Jiří ; Petruš, Josef (referee) ; Poláček, Petr (advisor)
This work deals with the application of selected types of fillers and monitoring their addition to the specific properties of the resulting composite material. The theoretical part of this work includes a general description of composite materials, and selected types of matrices, followed by a brief description of the characteristics of particulate composites and the effect of fillers on selected material properties. In the experimental part, samples of polyester resin were prepared to contain the given content of filler based on aluminium hydroxide (Al(OH)3), expanded glass, hollow glass microspheres, and fillers based on nitrogen and phosphorus compounds. Subsequently, the influence of the used fillers on the rheological properties, flammability of the material, on mechanical and thermomechanical properties was monitored. Flame test methods, bending test methods and dynamic mechanical analysis (DMA) were used to evaluate the samples. Finally, the measurement was supplemented by an analysis of fracture surfaces using a scanning electron microscope (SEM). The addition of additives improved the fire resistance of the prepared materials. The mechanical and thermomechanical properties of the prepared materials differed significantly depending on the applied fillers and their content.
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Particle Polymer Composite in structural details of the building envelope
Dostálová, Darina ; Lavický, Miloš (referee) ; Vokoun,, David (referee) ; Matějka, Libor (advisor)
Due to a European energy concept for reducing energy consumption and also the concept of sustainable development, there is a growing demand for reduced energy consumption during the operation of the building and hence increasing demands on the thermal and mechanical properties of the building envelope. For this reason, it is necessary to look for materials that could meet both thermal and mechanical properties, as well as mechanical resistance and loadability, especially for the application for the foundations of the house, the base of the house and for application to structural details for elimination of the thermal bridges between interior and exterior boundaries. The main motivation for choosing the topic of thesis was to find materials derived from recycled or secondary raw materials that would be suitable for manufacturing composite applicable for structural details in the envelope of the building and for insulating in humid environment. An economic and environmental aspect plays an important role in the choice of material. The main theme of the thesis is the laboratory manufacturing of a composite with a thermoplastic matrix derived from recycled plastic materials and waste foam as a phase. Has been developed a unique Waste-based Particle Polymer Composite (WPPC) made from recycled foam and polypropylene. However, before WPPC can be reliably used by construction designers, physical properties of WPPC must be accurately identified. Therefore, it was designed laboratory manufacturing system and sample testing system, it was studied thermal, mechanical, thermomechanical and moisture absorptivity of WPPC. Application of finished composite material with satisfying thermal insulation properties to structural details to eliminate the thermal bridge, was the next step. These are details of the unloaded, prefabricated balconies, windows, atics, as well as basement constructions and the heel of the central load-bearing wall, the terrain flooring and the staircase wall
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Application of functional fillers in composites: Effects of fillers content on the mechanical properties
Krhut, Jiří ; Petruš, Josef (referee) ; Poláček, Petr (advisor)
This work deals with the application of selected types of fillers and monitoring their addition to the specific properties of the resulting composite material. The theoretical part of this work includes a general description of composite materials, and selected types of matrices, followed by a brief description of the characteristics of particulate composites and the effect of fillers on selected material properties. In the experimental part, samples of polyester resin were prepared to contain the given content of filler based on aluminium hydroxide (Al(OH)3), expanded glass, hollow glass microspheres, and fillers based on nitrogen and phosphorus compounds. Subsequently, the influence of the used fillers on the rheological properties, flammability of the material, on mechanical and thermomechanical properties was monitored. Flame test methods, bending test methods and dynamic mechanical analysis (DMA) were used to evaluate the samples. Finally, the measurement was supplemented by an analysis of fracture surfaces using a scanning electron microscope (SEM). The addition of additives improved the fire resistance of the prepared materials. The mechanical and thermomechanical properties of the prepared materials differed significantly depending on the applied fillers and their content.
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Particle Polymer Composite in structural details of the building envelope
Dostálová, Darina ; Lavický, Miloš (referee) ; Vokoun,, David (referee) ; Matějka, Libor (advisor)
Due to a European energy concept for reducing energy consumption and also the concept of sustainable development, there is a growing demand for reduced energy consumption during the operation of the building and hence increasing demands on the thermal and mechanical properties of the building envelope. For this reason, it is necessary to look for materials that could meet both thermal and mechanical properties, as well as mechanical resistance and loadability, especially for the application for the foundations of the house, the base of the house and for application to structural details for elimination of the thermal bridges between interior and exterior boundaries. The main motivation for choosing the topic of thesis was to find materials derived from recycled or secondary raw materials that would be suitable for manufacturing composite applicable for structural details in the envelope of the building and for insulating in humid environment. An economic and environmental aspect plays an important role in the choice of material. The main theme of the thesis is the laboratory manufacturing of a composite with a thermoplastic matrix derived from recycled plastic materials and waste foam as a phase. Has been developed a unique Waste-based Particle Polymer Composite (WPPC) made from recycled foam and polypropylene. However, before WPPC can be reliably used by construction designers, physical properties of WPPC must be accurately identified. Therefore, it was designed laboratory manufacturing system and sample testing system, it was studied thermal, mechanical, thermomechanical and moisture absorptivity of WPPC. Application of finished composite material with satisfying thermal insulation properties to structural details to eliminate the thermal bridge, was the next step. These are details of the unloaded, prefabricated balconies, windows, atics, as well as basement constructions and the heel of the central load-bearing wall, the terrain flooring and the staircase wall
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Assessment of Crack Stability in a Quasi-brittle Particle Composite
Malíková, Lucie ; Klusák, Jan ; Keršner, Z.
Fracture behaviour of a crack in a particle (silicate based) composite is studied. The crack propagation depends not only on mutual elastic mismatch of matrix and aggregate but also the influence of the interfacial transition zone (ITZ) between the matrix and the aggregate is discussed. Various combinations of materials and geometry of matrix, aggregate and ITZ can improve or degrade fracture properties of the composite. Extensive numerical simulations on a basic 3-point-bending cracked specimen via the finite element method are performed in order to analyze the stress field near the crack tip. Linear elastic fracture mechanics approach is utilized in order to assess the crack stability and summarize several conclusions.
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